Polyurethane Roller Coating Process for Carpet Backing

ABSTRACT

A method for preparing carpet by using polyurethane to anneal secondary backing to a greige, comprising fibers attached to a primary backing using a roller application system. The greige is conditioned prior to coating and the polyurethane coated greige is contacted with the secondary backing and the laminate is tensioned and supported to maintain the laminate structure substantially through the polyurethane curing process.

This patent application is a continuation of U.S. application Ser. No. 15/782,265 filed Oct. 12, 2017, which claims priority to U.S. Provisional Application Ser. No. 62/460,372 filed Feb. 17, 2017.

FIELD OF THE INVENTION

The present invention relates to improved methods for adhering secondary backing to tufted or woven carpeting greige employing polyurethane adhesive systems.

BACKGROUND OF THE INVENTION

Polyurethanes are produced in four different principal forms including elastomers, coatings, flexible foams, and cross-linked foams. Polyurethane foams are produced by reacting isocyanate compounds with polyol compounds generally in the presence of catalysts, surfactants, and other auxiliary agents. At the start of polyurethane foam production, the reactive raw materials are held as liquids in large, stainless steel tanks. These tanks are equipped with agitators to keep the materials fluid. A metering device is attached to the tanks so that the appropriate amount of the reactive material can be pumped out. Generally, the ratio of polyol to isocyanate is about 2:1; and the ratio of components is strictly metered to control the characteristics of the resulting polymers. The reacting materials are then mixed and dispensed. Reaction between the isocyanate and the polyol, usually referred to as the gel reaction, leads to the formation of a polymer of high molecular weight. This reaction increases the viscosity of the mixture and generally contributes to cross-link formation. The second major reaction occurs between isocyanate and water. This reaction produces carbon dioxide gas which promotes foaming causing the volume of the urethane polymer to grow. In some instances, auxiliary blowing agents are added to further increase the volume of the polymer.

Both the gel and blow reactions occur in foams blown partially or totally with carbon dioxide gas. In order to obtain a good urethane foam structure, the gel and blow reactions must proceed simultaneously and at optimally balanced rates. For example, if the carbon dioxide generation is too rapid in comparison with the gel reaction, the foam tends to collapse. Alternatively, if the gel reaction is too rapid in comparison with the blow reaction generating carbon dioxide, the rise of the foam will be restricted resulting in high density foam. In practice, the balancing of these two reactions is controlled by the characteristics of catalysts, temperatures, and auxiliary agents used in the process.

It is customary in the carpet and rug industry to use various forms of filled and unfilled latex or polyurethane to coat the back of carpet. The coating is used to bond the face fibers to the primary backing and also thereby creating good tuft bind or fiber lock, and to bond secondary backing material to the greige (fibers/primary backing). For example, carpets having attached polyurethane layers as backing are described in U.S. Pat. Nos. 3,755,212; 3,821,130; 3,862,879; 4,022,941; 4,515,646; 5,604,267; 5,908,701; and 6,299,715. A key property of the carpet produced by these methods is annealing strength, or the force required to delaminate or separate the secondary backing from the carpet. In order to achieve optimal annealing strength, the secondary backing must be in direct contact with the greige, and a sufficient amount of adhesive must be between the greige and the secondary backing to thoroughly wet the fibers. A second key property is fiber lock, or a measure of the force necessary to pull face fibers from the carpet.

The most widely used annealing adhesive is latex. Latex is typically applied by methods involving roll over flatbed or roll over roll processes. Regardless, of the method used, the greige is coated with an adhesive precoat of latex, and the secondary backing, also coated with latex, is married to the greige and cured.

Although, latex is a popular adhesive, carpet prepared from latex displays numerous shortcomings. For example, the strength and hydrolytic stability of latex is less than optimal, and latex is less durable over time than alternative polymer systems such as PVC plastisol or polyurethane. Moreover, latex curing requires the evaporation of large amounts of water during cure, a process that is both expensive and energy intensive. Heating latex annealed carpet to achieve timely curing requires temperatures in at least the range of 70° C., and these temperatures may cause some carpet fibers and backing materials to shrink or change appearance and properties. To minimize the cost of latex adhesives, substantial quantities of filler material are added. The use of latex filler hinders the effective recycling of manufacturing remnants and used carpet at the end of its life cycle.

Alternatively, polyurethane adhesives have been employed to form carpet with superior annealing strength and other desirable physical properties. However, despite the advantages of polyurethane, cost and technical problems have kept it from widespread use in the industry as a coating, and even more rarely as a flexible foam.

Attempts to replace latex with polyurethane have resulted in a variety of new problems, requiring modifications to the usual latex annealing process. One striking example is the difficulty associated with placing polyurethane onto a greige material, while maintaining the necessary tack or adhesiveness to attach the second backing. After the pre-polymers have been mixed and polymerization begins, polyurethane soon begins to lose its adhesive properties. In addition, because the blow reaction substantially increases the volume of the polyurethane layer, even small irregularities in the application of the polyurethane components to the greige may result in unacceptable variations in the depth of the resulting polyurethane foam layer.

Loss of adhesiveness is generally not a problem with the use of latex. Conventional latex maintains its adhesiveness and viscosity during processing, even into the curing oven. Following application of latex adhesive to both the greige and the secondary backing the two components are married and as a result of the latex's properties, good temporary adherence of the secondary backing to the greige is observed. In the curing oven, the latex's viscosity does not drop significantly as a significant portion of water is evaporated. Thus, the secondary backing satisfactorily adheres to the greige.

On the other hand, polyurethane application from bulk troughs, common in latex systems, is made very difficult due to premature polymerization in the delivery line. Typically, polyurethane is applied as “froth,” polymerized prior to application and dispensed on the primary or secondary backing before the upstream edge of a doctor blade. However, unless the manufacturer guards against premature polymerization the delivery line tends to become clogged, thereby retarding the flow of polyurethane to the dispensing apparatus. The doctor blade will also tend to foul with polyurethane that adheres and cures, with a resulting loss of effectiveness. In addition, polyurethane begins to lose its adhesiveness soon after polymerization begins unless the manufacturer controls the polymerization rate by using heat sensitive catalysts or other chemical agents designed to maintain the viscosity of the polyurethane. Regardless of the manufacturer's attempts at controlling premature polymerization, the manufacturer has only a finite amount of time after the pre-polymers (polyol and isocyanate) have been mixed in which to apply the polyurethane and contact the greige to the backing before the polymer begins to lose its adhesive properties.

When chemical agents were previously added to control premature polymerization and maintain viscosity to enable the polyurethane to penetrate the fibers, achieve good tuft bond, and maintain adhesiveness to affix the secondary backing, the resulting mixture typically was not quickly cured without heat from ovens. If dry heat is applied to a polyurethane coated greige before marrying the secondary backing the polyurethane will tend to form a crust-like surface with little tack or adhesiveness. Oven curing adds time and cost to the finishing process, and can also adversely affect some fibers by matting or shrinkage.

In an attempt to combat the rapid loss of adhesiveness, manufacturers have applied one coating of polyurethane to the greige as fiber lock and a second coating of polyurethane just prior to contacting the secondary backing to insure sufficient adhesion between the backings. Even with the additional polyurethane, the slow advancement of most commercial carpet lines, combined with the inherent lack of adhesiveness associated with polyurethane, does not allow for the desired adherence between the greige and the secondary backing without the use of considerable and expensive quantities of the pre-polymers.

To extend the coverage of a given quantity of polyurethane pre-polymers, it is customary to add filler material to the mixture. However, filler materials are generally abrasive and complicate the application of the polyurethane mixture by either wearing on applicator parts or increasing the tendency of lines and applicators to clog or apply unevenly. Furthermore, frothing the pre-polymer mixtures containing substantial amounts of filler material generates heat, and at high filler levels frothing will activate heat sensitive catalysts and begin the polyurethane curing process.

Curing the backing to the greige is also complicated because of the considerable decrease in viscosity of the polyurethane prior to cure. The viscosity of the polyurethane, and likewise its adhesiveness, may decrease to only 10% of its initial value prior to application of the secondary backing as the catalyzed polyurethane-foaming reaction begins to exert its effect. The greatest decrease in viscosity is often exhibited over the temperature range from ambient to about 70° C., where the polyurethane catalysts are not optimally active. As a result, if the initial adherence of the secondary backing to the greige is insufficient the secondary backing may separate during this period of low viscosity.

In an attempt to address the problems associated with the use of polyurethane several changes to the underlying process have been disclosed. For example, U.S. Pat. No. 6,264,775 offers the addition of various chemical thickening agents to the polyurethane to maintain viscosity and adhesiveness. Another process provides for the use of multiple applications of polyurethane to the primary backing prior to joining the secondary backing. See e.g., U.S. Pat. No. 6,299,715. Still another technique disclosed in U.S. Pat. No. 6,299,715, is the application of both polyurethane to the primary backing and another tacky composition to the secondary backing prior to joining the two backings. In U.S. Pat. No. 4,515,646, refrigerated isocyanate and polyol components were used without catalysts to prevent premature polymerization. WO 03/039869 proposed spraying a substantially water-free polyurethane on the greige and effecting the blow and curing with steam. None of these techniques was favored over standard latex based carpet laminates, primarily due to the increased cost and complexity associated with building and using separate manufacturing lines to implement the new technologies, or the failure of the techniques to work in a production environment. However, U.S. Pat. No. 7,368,008 disclosed an effective roller-based polyurethane foam carpet annealing process requiring only a single application of the polyurethane, while providing acceptable fiber lock and annealing strength, without using excessive quantities of polyurethane to provide sufficient annealing strength, and that can be cured without an oven.

SUMMARY OF INVENTION

The present invention pertains to an improved polyurethane carpet annealing system that may employ only a single application of polyurethane, pretreating or conditioning the greige, speeding the polyurethane cure process with live steam, and utilizing pressure or support to secure the secondary backing against the polyurethane coated greige until backing adhesion results. The carpet produced by the process provides secondary backing adhesion without the use of large quantities of polyurethane and without the expensive oven curing step common in other annealing systems.

BRIEF DESCRIPTION OF DRAWINGS

FIG. 1 illustrates a roller-delivered polyurethane coating process of the prior art s practiced in U.S. Pat. No. 7,368,008.

FIG. 2 illustrates a roller arrangement for applying polyurethane to the greige goods from the prior art.

FIG. 3 is an alternative configuration of the roller-delivered polyurethane coating process from the prior art.

FIGS. 4A-4E are yet other alternative configurations of the roller-delivered polyurethane coating process from the prior art of U.S. Pat. No. 7,368,008 that can be improved by aspects of the present invention.

FIG. 5A is a schematic of a heated drum configuration useful in curing the polyurethane adhesive in an embodiment of the invention.

FIG. 5B is a schematic of a headed drum configuration useful in curing the polyurethane adhesive in an alternative embodiment of the invention.

DETAILED DESCRIPTION OF THE INVENTION

The present invention is designed to improve the annealing of secondary backing to tufted or woven carpeting utilizing a polyurethane adhesive system.

FIG. 1 illustrates a dispensing apparatus for applying mixed polyurethane onto the greige as described in U.S. Pat. No. 7,638,008. The greige 11, is fed in direction 12 past the polyurethane mixture dispensing apparatus 10. The dispensing apparatus 10 preferably comprises a polyurethane dispensing head 21, fed by a polyol tank, an iso tank, and a catalyst tank. Optimally, catalysts and other additives may be selected that can be premixed with one of either the polyol or iso mixtures.

Polyol tank contains polyol mixed with filler and surfactants, such as silicone. The iso tank contains isocynate. The catalyst tank contains one or more catalysts and a small amount of water. Typically, there will be between two hundred fifty and five hundred parts filler per hundred parts of polyol and between about 0.05 to 3.0 parts of water per hundred parts of polyol, with the water being added to facilitate the “blow” reaction. Contents of the polyol, iso and catalyst tanks are pumped to polyurethane dispensing head 21. The dispensing head 21 may include multiple dispensing spouts and may be moved transversely above the rollers 23,26 to create a more evenly distributed puddle 24. The temperature of the polyol mixture may be controlled either by refrigerating the entire polyol tank or by passing tubing from the tank through a heat exchanger to achieve the desired temperature prior to mixing.

All of the ingredients may be temperature controlled as described in connection with the polyol mixture above. In addition, there may be other additives such as stabilizers, antioxidants, antimicrobials, anti-mildew agents, colorants, flame retardants, penetrants, and chain extenders, all depending upon the characteristics desired in the resulting foam.

The illustrated polyurethane dispensing head 21 dispenses polyurethane mixture into a puddle 24 extending transversely across a substantial width of the greige 11. The puddle 24 is formed by the proximity of application roller 23 and drive roller 26. In the illustrated embodiment, the application roller 23 turns clockwise pulling a polyurethane coating downward from the puddle onto the greige 11. The illustrated drive roller 26 turns counter-clockwise tending to pull the greige 11 forward in the direction 12 of the annealing process. The thickness of the polyurethane coating applied may be adjusted by speeding the rotation of the application roller 23 to bring down more polyurethane. The greige 11 may be pressured against one or both of application roller 23 and drive roller 26 by support 27. Preferably the greige 11 passing over the surfaces of application roller 23 and drive roller 26 effects a wiping action on the rollers 23, 26 and minimizes polyurethane buildup. Wiping action is naturally effected on application roller 23 because it rotates its surface in the opposite direction to the travel of the greige 11. Wiping action on the drive roller 26 is preferably effected by rotating that roller somewhat faster than the greige 11 is allowed to travel through the secondary backing process.

Prior to passing under the rollers 23,26, the greige 11 is preferably conditioned to be a receptive target for the polyurethane mixture. One form of conditioning is physical and may involve only the use of a tenter frame to pull the greige 11 wide as it approaches the rollers 23,26. Pulling the greige 11 wide on a tenter frame tends not only to minimize any wrinkling of the greige 11 as it passes beneath the rollers 23,26 that would lead to uneven application of polyurethane, but also tends to separate the spacing of the backstitches and woven yarns in the backing of the greige 11 to facilitate penetration of the polyurethane mixture.

Another physical treatment involves the policing of the back of the greige 11. Often in the production of cut pile or cut/loop tufted carpet, some short yarn segments will become detached and may lie on the back of the greige, loosely held by fibers or electrostatic charges. If these loose yarn pieces remain on the greige when it is coated, polyurethane may be applied unevenly, or the rollers 23,26 may loosen and rotate the yarn pieces into the puddle 24 where the yarn may cause clumps of polyurethane to form and interfere with the coating process. To police the back of the greige, a strong vacuum or blower may be used to dislodge loose yarn segments resting on the backstitch side 15 of the greige.

Another physical conditioning of the greige 11 is to ensure that it proceeds to coating at an appropriate and even temperature. Temperature affects the speed of the polyurethane curing and the starting temperature of the greige 11 as it enters the annealing process can be affected by several factors. For instance, the general temperature maintained inside a coating plant may vary by over 10° C. from summer to winter. In addition, rolls of greige for coating may have only recently been unloaded from trucks (with no climate control) and may vary in temperature from the outer layer to the center of the roll. By passing the greige 11 over heating or infrared elements before proceeding to the rollers 23,26 a relatively uniform starting temperature can be maintained so that the polyurethane coating and curing proceeds in a standardized fashion.

In addition to physical treatment, adhesion treatment may also be applied to the greige or secondary backing material. A typical adhesive treatment is a plasma treatment utilizing a corona apparatus, with a transverse linear array of electrodes to alter the surface energy of the backstitch side 15 of the greige 11, or to alter the face of the secondary backing 55. Atmospheric or chemical plasma treatments may similarly be employed to similar effect, though flame plasma treatments would be disfavored due to the heat and potential fire hazard.

Another adhesive treatment is the misting of the back of the greige 11 or secondary backing with a polyurethane compatible surfactant to facilitate the penetration of the greige.

The adhesion of the polyurethane material to the greige 11 may be furthered by the use of a roller, a doctor blade, controlled vacuum, blower, ultrasonic waves or an air knife, and in some instances, by thinning the viscosity of the polyurethane material. An ultrasonically vibrated doctor blade is preferable when actually contacting the polyurethane material as the vibration tends to prevent adhesion and buildup on the doctor blade. Penetration into the greige is critical to achieving acceptable tuft bond and annealing strength.

By placing the mixing directly at the polyurethane dispensing head 21 closer to the actual application of the polyurethane components, there is less time for a reaction to occur before the components are on the greige 11, thereby reducing the chance of clogging the dispensing apparatus. The head 21, or preferably a plurality of transversely spaced heads 21, may move laterally across the greige 11 between the application roller 23 and drive roller 26 to keep the puddle 24 relatively even. Even with this arrangement, the polyurethane mixture may be thick and viscous so that an extremely strong or reinforced assembly is useful in supporting the rollers 23, 26 to prevent their longitudinal movement.

FIG. 1 illustrates the carpet finishing process with the greige 11 with carpet face 10 downward fed onto a tenter roll 13 that keeps the greige 11 spread to its full width while directing the greige 11 to rollers 23, 26 of the dispensing apparatus 10. The carpet face 14 is advanced over the support 27 using pulling rollers 16.

In FIG. 1, after the greige 11 and especially the backstitch side 15 has been conditioned, a layer of polyurethane pre-polymer mixture is deposited onto the primary backing backstitch side 15 as it passes over support 27 using rollers 23, 26. Preferably, the polyurethane is applied to this side of the primary backing 15 at an area concentration of 3 to 5 ounces of polyurethane, or about 6 to 40 ounces total mixture including fillers and additives, per square yard or in a more preferred concentration of about 14 ounces total mixture per square yard. The 3 to 5 ounces per square yard range is the weight of only the polyurethane components, and does not include the weight of optional additives such as fillers or thinners that are useful aids to effective and economical coverage. The polyol and isocyanate pre-polymer components are laid onto and wiped across the primary backing 15 by application roller 23. The pre-polymers are preferably mixed just prior to dispensing from the polyurethane dispensing head 21 and subsequent application to the primary backing 15.

At this time of initial application, only a small amount of water has been added which reacts and serves as a blowing agent. According to this method, the polymerization process does not begin to occur until just prior to the exit of the polyurethane components from the polyurethane dispensing head 21, and the polyurethane is quickly applied by rollers 23, 26 to the backing 15. This process and pressure between application roller 23 and/or drive roller 26 and support 27, together with the conditioning of the greige 11, allows the relatively low viscosity polyurethane to deeply penetrate the fibers in the backstitch and primary backing, resulting in excellent fiber lock characteristics. Immediately after application of the polyurethane, optional aids to penetration such as the previously mentioned doctor blades, vacuums, or blowers may be most effectively employed, as may be particularly desired when processing greige tufted with heavy yarns.

The polyurethane coated greige 11 is then optionally passed across a steam box 150, that is adjustable with respect to steam temperature, volume, and slot size. Steam box 150 adds more water to facilitate the blow reaction and heat to aid in accelerating the gel reaction. In addition, the steam serves to enhance blooming of the yarns passing through the primary backing for deeper penetration and assures a more level coverage of polyurethane. A fume hood 155 is placed above the steam box 150 to capture escaping volatiles released with the steam. In lieu of a steam box 150 and fume hood 155, live steam may also be applied by a transverse linear array of nozzles. Conspicuously absent at this stage of the process is an oven curing step. Instead, heat may advantageously be applied directly to the carpet by passing it around oil or steam heated drums as reflected below in connection with FIGS. 3-5.

An oven is not necessary in the process because the polyurethane components are essentially kept separate until they are applied to the primary backing 15, therefore there is no need to dope the polyurethane components in order to severely slow the rate of polymerization. However, rather than as illustrated in FIG. 1, steam or other heat is preferably applied immediately before and after the coated greige 11 is joined with the secondary backing 55. Temperatures are generally maintained within 40° C. of ambient temperature or in a more preferred embodiment within 20° C. of ambient temperature, during the carpet manufacturing process.

After applying the polyurethane coating, and preferably before substantially heating the coated greige 11, the coated greige 11 is rapidly pulled to merge rolls 160 a, 160 b where the secondary backing 55, supplied from roll 60, contacts the coated greige 11. Due to the short time that elapses between the initial application of polyurethane and the merger of the secondary backing 55 with the coated greige 11, the polyurethane possesses sufficient tackiness to anneal the secondary backing in place.

The merge rolls 160 a, 160 b may not only contact the secondary backing 55 to the coated greige, but also serve to gauge the height of the blown polyurethane, preferably at no more than about one-eighth inch in height, and to halt any additional volumization of the polyurethane. This is due to the merge rolls 160 a, 160 b compressing the blown polyurethane and rupturing many of the still closed cells within the polyurethane. In a preferred embodiment, the secondary backing is a non-woven needle punch fabric or spun bonded fabric of nylon, polypropylene, polyester, polyethylene or similar fibers and may have a calendared surface. A spun bond fabric having a weight of between about 1.5 and 4 ounces per square yard is a suitable and inexpensive secondary backing. The absence of an oven curing step facilitates the use of relatively low melting point materials. Woven fabrics are also useful as a secondary backing in fabrics produced using the polyurethane roller coating process.

The independence gained by controlling the mixing of polyol and isocyanate has led to the removal of a curing station. The excision of this step has dramatically improved the processing speed of laminated carpets, cutting manufacturing time by as much as 50-60% without sacrificing the annealing strength or fiber lock properties of the carpet. The annealed carpet can then be cooled briefly on accumulator rolls 190 and rolled on take up roll 200 for storage and transport, typically in lengths of up to about 600 feet.

A number of variations to the described process are possible. For instance, the carpet may be fed over a vacuum or ultra-sonic wave device in order to pull the viscous polyurethane deeper into the primary carpet backing after application of polyurethane by application roller 23. Also, if the heat from the steam box 150 is used prior to joining the greige 11 to the secondary backing 55 and the steam accelerates polymerization so that the polyurethane film has cured sufficiently to lose much of its tackiness, the secondary backing 55 may require coating to enhance its adherence to the coated greige product 11.

The secondary backing 55 may also be applied at a much earlier stage in the process, so that immediately after the polyurethane layer is deposited on the backing side 15 of the greige as it passes under the drive roller 26, the secondary backing 55 may be applied, preferably by transition around a doctor bar or merge roller 160 c which causes the secondary backing 55 to come into contact with the polyurethane layer as the reaction of the prepolymers is just beginning. In this case, live steam may be applied to the married greige 11 and secondary backing 55 to jump start the polyurethane reaction before the carpet contacts a heated drum 40 (shown in FIG. 3).

In another adaptation of the processes depicted in FIG. 1, it is possible to form an attached cushion on the polyurethane coated greige 11. To accomplish this, slightly more polyurethane mixture is deposited, typically by running the rollers 23, 26 in FIG. 1 at faster speeds, to deposit about 25-40 ounces of polyurethane mixture per square yard of greige. By opening the gap between the rollers 23, 26 even greater amounts of polyurethane mixture may be deposited, but typically not more than about 55 ounces of polyurethane mixture per square yard. In addition, the speed of the production line is slowed or its configuration altered, as by adding an accumulation device, to provide more dwell time to allow the additional amounts polyurethane to blow and cure.

Because much of the polyurethane mixture is embedded in the greige, this is not an efficient use of polyurethane materials. However, for the creation of thin pads, this application of a unitary layer to lock the tufted fibers in the greige and produce a padded product is more economical than adding a separate process. Accordingly, the relatively heavy layer of polyurethane is allowed to blow to a height of slightly more than about one-eighth to three-sixteenth inches and gauge rolls are set to gauge the height of that attached pad or cushion.

FIG. 2 shows an example of roller coating station 10 from U.S. Pat. No. 7,638,008 in greater detail with greige goods 11 passing over first directional roller 116 a, downward and around clockwise driven application roller 23 and counterclockwise driven drive roller 26 upward to second directional roller 116 b. Spacing between application roller 23 and drive roller 26 is adjustable utilizing linkage 123. As the greige 11 passes beneath rollers 23, 26 polyurethane is applied from puddle 24. Polyurethane puddle 24 is dispensed from dispensing head 21 with one or more mix heads mounted for transverse movement where feeds from a polyol tank including polyol and other ingredients, typically including filler and catalysts, is combined with isocyanate and additional catalysts. The number of dispensers 21 can vary and typically one mix head and dispenser for each meter in width of carpet is preferable. The polyol and isocyanate material coming to the mix head should stay at a constant temperature during the processing of a run of greige. The preferred temperature is about 30-35° C., but in connection with some polyurethane mixtures and some carpet products, optimal results may be obtained at higher or lower temperatures. The temperature 35° C. is utilized to thin or lower the viscosity of the polyurethane mixture coming from the dispenser 21 and improve the penetration of the polyurethane in the primary backing and back stitches of the yarns of the greige 11. Because of the tendency of polyurethane to adhere to surfaces that it contacts, pressurized air is a preferred method of containing and shaping the polyurethane in the puddle 24.

The application roller 23 and drive roller 26 are precision rollers designed to apply the polyurethane material evenly across the width of the greige 11 and to maintain a consistent rate of application of polyurethane to each square yard of carpet. Because the length of the rollers is typically approximately four meters, and up to six meters in some cases, special construction may be necessary to keep the gap between rollers 23, 26 uniform over their full length. In order to keep the puddle 24 between the rollers 23, 26, one roll runs clockwise and the other roll runs counterclockwise. In the embodiment illustrated in FIG. 2, the application roller 23 runs clockwise and the drive roller 26 runs counterclockwise, and to maximize the roller wiping action it is preferred to have the clockwise roller run at a slower speed than the speed at which the greige 11 is fed while the counterclockwise roller runs faster. It will be understood that roller speeds will vary depending upon the construction of the greige product and the amount of polyurethane material to be applied. For instance, loop pile greige goods are generally easier to process to achieve good tuft bind and delamination strength than cut pile goods. In addition, greige tufted with finer yarns is generally more easily penetrated by a polyurethane mixture than greige tufted with thick or berber-like yarns.

The rollers 23, 26 can be run at a variety of speeds as long as the rollers wipe themselves clean, generally by the feed rate of the processed greige 11 being either faster or slower than the speed of rotation of rollers 23, 26, and thereby avoid any buildup on the rollers. The amount of polyurethane material applied from puddle 24 is determined by speed of the rollers 23, 26, the width of the gap between the rollers, and the viscosity of the polyurethane material. It is generally preferred that the viscosity of the polyurethane material be constant and the gap between rollers 23, 26 be kept constant and any changes in the amount of polyurethane material applied being controlled by changing roller speeds. However, adjustments to roller spacing or viscosity may be used in some instances.

In FIG. 2, a support roller 127 is also shown in order to apply upward pressure against the greige 11. The pressure applied by roller 127 is adjustable by controlling piston 128 that communicates upward pressure to the ends of roller 127 by means of linkage 129. The pressure applied by support roller 127 also affects the amount of polyurethane material being applied to the greige 11 and the pressure should be set at a constant during a run of carpet. Certain greige products will require a different pressure setting from the support roller 127 for optimal performance. Alternative or supplementary support structures may be used with or in place of a support roller 127, depending upon the greige 11 and precise formulation of the polyurethane material in any particular instance.

Turning then to FIG. 3, an alternative arrangement of the polyurethane roller applied backing system is illustrated. The greige goods 11 proceed about a J-box 92 to allow for conditioning and to assist in controlling the carpet's entry into the roller applicator 10. After the greige 11 is coated with polyurethane, it passes by ultrasonic doctor blade 36 where the ultrasonic vibrations of the doctor blade prevent adhesion of the polyurethane material which would foul the blade and the pressure of the doctor blade 36 improves the penetration of the polyurethane mixture. The greige 11 then optionally passes over steam box 150 and below fume head 155 and thereafter immediately has secondary backing 55 married to it by pinch rollers or nip rolls 160 a, 160 b. Thereafter, the carpet passes to a heated drum such as heat can 40 which is preferably a hot oil can but could also be steam heated. Heat can 40 helps iron the secondary material 55 to the greige 11 and also accelerates the cure process allowing the carpet to be run at higher speeds and in a shorter distance to roll-up. The number and size of heat cans 40 may vary depending upon the run speed and space desired. No heat can 40 is required as additional heat is not necessary for curing a polyurethane mixture, merely time, so that only tenter frames and accumulators may be utilized if necessary. Indeed, after passing about heat can 40, the carpet is shown proceeding to tenter system 52 and accumulator 190 and thereafter to the roll-up of the finished carpet 200.

The timing of the marriage of secondary backing 55 to the coated greige 11 is critical. The reaction of the polyurethane material must be sufficiently complete to marry the secondary backing 55 to the greige 11. There is a relatively brief window in which the polyurethane material is sufficiently sticky to form a strong bond to the greige 11. If the greige 11 arrives too early, the adhesion to the backing 55 and resulting overall product will not be as strong as possible. Similarly, if the greige 11 arrives too late at the marriage point, the polyurethane material will be over-cured and the secondary backing 55 will not stick to the greige 11. The state of reaction of the polyurethane material at the marriage point can be changed by adding heat to the greige prior to the marriage point, changing the catalyst package to accelerate or decelerate reaction and curing, or adjusting the distance between the application rollers 23,26 and the marriage point. In the embodiment of FIG. 3, it is preferred to utilize a standard catalyst package, a standard distance to the marriage point, and to adjust the heat and water applied by the steam box 150 to increase the heat and accelerate the reaction as necessary or shut off the heat and slow the reaction, in order to have the polyurethane material at the appropriate state to marry the greige 11 with the secondary backing 55.

The embodiments of FIGS. 4A-4D illustrate alternative constructions that adjust the state of reaction of the polyurethane material at the marriage point by providing a method to adjust the distance between the application rollers 23, 26 and marriage point. Specifically, the unbacked greige 11 is passed through tenter frame 91 and J-box 92 to condition and control the greige prior to application of the polyurethane material. The greige 11 proceeds past application rollers 23, 26 and then to a moveable tenter roll 147 adjustable between a low position 47 and a high position 247 shown in phantom, and the illustrated intermediate position 147 to allow the length of coated greige 11 intermediate the application rolls 23, 26 and nip rolls 160 a, 160 b at the marriage point with secondary backing 55 to be increased or decreased and thereby effect the completeness of the reaction of the polyurethane material at the marriage point. Either nip rolls 160 a, 160 b or subsequent rubber coated pressure rolls 66 a, 66 b should be pressure controlled to ensure a complete marriage of the secondary backing 55 to the coated greige 11. Thereafter the carpet again passes around first heat can 40 and second heat can 41 to iron the secondary backing 55 to the greige 11 and speed the curing process. The carpet then goes through accumulator 190 to roll-up as the finished carpet product 200.

FIG. 4B illustrates the polyurethane application, marriage and heating of the FIG. 4A in greater detail. FIG. 4C illustrates an alternative construction of the embodiment of FIG. 4B wherein the support rolls 127,137 in the support or backup structure 27 of FIG. 4B are replaced by air bladder 227. The air bladder 227 can more closely conform to the shape of the application and drive rollers 23, 26 and preferably urges a Teflon belt or other low friction material against the face 14 of the greige 11 and provides good results for some products. Again, the moveable tenter roller 147 controls the distance between the application of polyurethane material and the marriage point at pinch rollers 160 a, 160 b and the carpet proceeds around first and second heat drums 40, 41 which are typically heated to at least 70° C., and are optimally kept at a temperature of about 85° C. to 90° C.

FIG. 4D shows yet another alternative configuration for the application of polyurethane material through rollers 23, 26. Again, the greige passes about tenter frame 91 and J-box 92 prior to proceeding to polyurethane dispensing apparatus 10. The greige 11 can be additionally conditioned by passing through a pattern straightener or steam box if desired. The greige 11 then proceeds beneath rollers 23, 26 which supply polyurethane material from puddle 24. Penetration of the polyurethane material is increased by the pressure of ultrasonic doctor blade 36 against the coated greige 11 as it passes over support roller 64. Then blower 37 and vacuum 38 also act upon the polyurethane material to increase penetration of the fibers of the yarn back stitch and any primary backing fabric comprising the greige. Moveable tenter roll 147 controls the distance between the polyurethane application apparatus 10 and marriage point at nip wheels 160 a, 160 b and the reaction time of polyurethane materials can be additionally controlled by the temperature of the air applied from blower 37. The carpet again proceeds around heat cans 40, 41 to iron the secondary backing 55 to the greige 11 and accelerate the cure process. In some cases, shearing machines, trimmers, and other finishing equipment can be located between heat cans 40,41 and roll up.

Finally, FIG. 4E illustrates the application of polyurethane to both the greige 11 and the secondary backing 60. The application of the polyurethane mixture to the greige 11 from the roller coating station 10 is just as described in connection with FIG. 4D. A steam box 150 and fume hood 155 accelerate the blowing and curing of the polyurethane. In addition, another chemically reacting polyurethane foam (with less filler and more water) is applied by head 121, to the secondary backing 55. This secondary backing 55 is preferably spunbond or woven fabric or sheet plastic. A self-cleaning doctor blade 35 or air knife evens the application of the polyurethane to the backing. The polyurethane mixture with less filler and more water, but still only about 2-5 parts water per 100 parts of polyol, tends to blow and cure more quickly as a lighter foam. Since this foam material is not lost into the greige, it is a more efficient use of the polyurethane and is particularly more efficient with the height of the foam pad will reach a quarter of an inch or more.

The coated greige 11 and secondary backing 60 then lay together on a tenter frame 52, where they bond and proceed through oven 90 to quickly bring the polyurethane to a fully risen or blown state. At this point, the carpet is re-gauged with graduated gauging rollers 261 to a selected height. The result is a cushioned carpet product.

In operation, the marriage of the secondary packing 55 to greige 11 is critical. As the greige is typically preheated by infrared, steam, or a heat box, before application of the polyurethane adhesive 24, this causes polyester or other fibers to bloom and be receptive for the adhesive mixture. However, the adhesive will typically require a catalyst to slow the curing the time so that the puddle of adhesive does not significantly cure before application to the greige 11. As result, when the coated greige meets the secondary backing 55 and begins to pass around a heated can 40, there is not an instantaneous complete curing and bonding between the greige 11 and secondary backing 55. Indeed, when the greige 11, polyurethane, and secondary backing 55 are contacted, it may require approximately one minute of heat from a can, typically a hot oil or steam heated drum at about 290° F. to sufficiently complete the curing of the polyurethane adhesive such that there is no likelihood of separation of greige and secondary backing during further processing. Live steam may be applied prior to the heated drum 41 in order to “jump start” the curing of the polyurethane.

Even so, with a coating line running at about 75 linear feet of greige 11 per minute, contact between the greige 11 and secondary backing 55 should be uniformly maintained throughout the circuit around an entire 10-foot diameter heat can 40 or for the entirety of the circuit around a smaller heat can and the beginning of the circuit of a second heat can 41. As illustrated in FIG. 5A, it can be seen that coated greige and secondary backing contacts the heated can 40 it is at approximately the 11:30 position (if the side of the heat can were a clock face) and the curing carpet proceeds counterclockwise to about the 1:00 position and then proceeds to the second heated drum 41 for a similar circuit before proceeding to the cutting apparatus 212 to trim selvage and the accumulator 190 and the rolled finished carpet 200. The tension applied to the married greige 11 and secondary backing 55 is critical as if the tension on the greige is insufficient, there will be folds and wrinkles while if the tension is too great, it will pull the greige and secondary backing in different amounts to their varied elasticities and cause separation.

In addition, as the secondary backing with greige adhered proceeds around the first heated can 40, the weight of the carpet tends to cause the greige 11 to separate from the secondary backing 55 along the lower half of the heated can 40, as it moves counterclockwise from 9:00 to 3:00. The weight of the greige is most noticeably unsupported between about 8:00 and 4:00 on the can 40 so the greige, if of any significant weight, may separate from the secondary backing 55. The secondary backing 55 is usually a very lightweight woven or non-woven fabric that is easily held against the surface of the heated can 40. However, in a heavy or densely tufted greige 11 will tend to be pulled to separate from the secondary backing 55 by its own weight as it proceeds around the lower half of the heated can 40.

In order to prevent these problems, two critical tools are deployed. First, a load cell, typically gauged between 0 and 450 lbs., acting at about guide wheel 61 near the placement of the married carpet on the heat can 40 provides signals to keep the heated can 40 rotating at the correct speed to maintain appropriate tension on the greige. Secondly, a support, possibly in the form of press roller 261, is set beneath the heated can 40 to press the greige 11 against the secondary backing 55 around the 4:00 or 5:00 position. This keeps a heavy greige from dropping away from the secondary backing that is held against the heated can 40. Such gravitational separation is a most significant problem when the greige is relatively heavy as when carrying a dense or high yarn pile, and may present a few problems with a low density light weight yarn tufted to a relatively short pile height. Even so, the use of press roller or similar support along the lower half of the first heated can 40 is particularly useful in preventing separation whenever the polyurethane adhesive has not yet cured sufficiently to maintain a permanent bond between the secondary backing and the greige.

FIG. 5B illustrates a further variation in which the tenter roller is set at nearly the lowest possible position 47 a to still achieve effective polyurethane coating and the coated greige proceeds quickly to heated drum 40. Due to the short distance between the polyurethane coater and the heated drum, the polyurethane reaction is advantageously jump-started with live steam from steam nozzle array 250 extending across the polyurethane coated side of greige 11. Then the secondary backing 55 may preferably receive an adhesion treatment, as by corona electrode array 240, and is married to the coated greige at guide wheel 61 which serves both as a marriage roller and also, via load cell in communication with the curing line controls, to maintain appropriate tension on the secondary backed greige as it proceeds around heated drum 40. Additional press roller 260 helps ensure the marriage of the greige to the secondary backing 55 and as in FIG. 5A, a support, such as press roller 261 holds the greige against the secondary backing when it is in its unsupported position around the lower half of heated can 40.

In the foregoing embodiments, the figures have been simplified for clarity and to ease viewing and understanding. In commercial embodiments, additional devices, e.g. drive motors, tension devices, etc. will be required.

Polyurethane prepolymers useful in the practice are prepared by the reaction of active hydrogen compounds with any amount of isocyanate in a stoichiometric excess relative to active hydrogen material.

The prepolymer formulations include a polyol component. Active hydrogen containing compounds most commonly used in polyurethane production are those compounds having at least two hydroxyl groups or amine groups. However, any active hydrogen containing compound can be used with the present invention, and indeed some soy based oils can be used.

In practice, preferably at least 50 weight percent of the active hydrogen compounds used to prepare the polyurethane is a polyol having molecular weight of from about 100-400.

The polyisocyanate component of the formulations can be prepared using any organic polyisocyanates, modified polyisocyanates, isocyanate based prepolymers and mixtures thereof. These can include aliphatic or aromatic isocyanates. Preferably the isocyanate used to prepare the prepolymer formulation of the present invention is methyl diisocyanates such as Bayer's 142L or Dow p901 or blends of equal type.

Catalysts suitable for use in preparing the blown polyurethanes include tertiary amines, and organometallic compounds and mixtures thereof. For example, suitable catalysts include stannous octoate, triethylenediamine, N-methyl morpholine, like compounds and mixtures thereof. The catalysts do not necessarily need elevated activation temperatures or other promoters to initiate polymerization.

Surfactants can be useful for preparing a stable dispersion of the present invention. Surfactants useful for preparing a stable dispersion can be cationic, anionic, or non-ionic surfactants. Preferably the surfactants used to prepare the prepolymer formulation are silicone surfactants such as Dow Corning DC-194 or Union Carbide's L-540. A surfactant can be included in a formulation in an amount ranging from about 0.01 to about 7 parts per 100 parts by weight of polyurethane component.

A polyurethane adhesive optionally includes a filler material. The filler material can include conventional fillers such as milled glass, calcium carbonate, aluminum trihydrate, barium sulfate, fly ash, dyes and pigments or fire retardants (aluminum trihydrate and Tris polyolefin glycol). Preferably the filler can be present in an amount ranging from 0 to 600 parts, and more preferably between 100 and 500 parts, per 100 parts of the polyol component. With the use of thinning and penetration enhancing additives, it is possible to achieve satisfactory results with as much as 550 to 600 parts filler to 100 parts of polyol. According to the invention, utilizing greige goods comprising a backing fabric tufted with level loop yarns and the application of polyurethane materials containing a combination of polyol, isocyanate, and catalyst at a rate of 90 grams per square yard, together with fillers, penetrants and other extenders, the resulting carpet achieves a tuft bind of at least 6.25 pounds measured according to ASTM standards and delamination strength in excess of at least 2.5 pounds. Indeed, when using spun bonded polypropylene secondary backing material, which is possible due to the absence of oven curing, the secondary backing will often tear prior to delamination. When the same rate of 90 grams of isocyanate, polyol and catalyst per square yard is applied to greige comprising a backing fabric tufted with cut pile yarns, the tuft bind exceeds 3 pounds per square inch and delamination strength again achieves at least about 2.5 pounds per square inch. When the rate of application of the isocyanate, polyol and catalyst material is at the rate of 150 grams per square yard, the tuft bind of level loop carpet may reach 15 pounds and the resulting carpet far exceeds all customary structural standards required for residential or commercial carpet. Furthermore, the resulting carpet utilizing the polyurethane binder to attach the secondary backing is mold and mildew resistant, non-allergenic, easier to install, and less subject to degradation when subjected to extreme heat and cold. In addition, the manufacturing process utilizes a minimal amount of water compared to the process of utilizing a latex binder, utilizes less energy, and results in less waste products.

Generally, any method known to one skilled in the art of preparing polyurethane froths can be used in the practice of the present invention to prepare a polyurethane froth suitable for preparing a carpet of the present invention, however, typically only one of the prepolymer mixtures is frothed, since the use of water as a blowing agent provides ample volume to the polyurethane. It is also possible to froth the polyurethane mixture in the mix head by adding air or inert gas at that point.

Although a preferred embodiment of the present invention has been disclosed herein, it will be understood that various substitutions and modifications may be made to the disclosed embodiment described herein without departing from the scope and spirit of the present invention as recited in the appended claims. 

What is claimed is:
 1. A method for manufacturing a laminated carpet product using a polyurethane roller annealing system to join a greige having a face and an opposed backstitched side with a secondary backing comprising: (a) feeding a greige; (b) physically conditioning the greige; (c) applying a polyurethane mixture with the roller annealing system as the greige is moved laterally with respect to the rollers to form a coating on the backstitch side of the greige; (d) contacting a secondary backing to the polyurethane mixture coated backstitch side of the greige to form a backed greige; (e) feeding the secondary backing side of the backed greige substantially around the circumference of a heated drum; (f) tensioning the backed greige to tend to hold the backing side against the surface of the heated drum; (g) supporting the greige on the lower side of the heated drum to hold the greige against the drum.
 2. The method of manufacturing a laminated carpet product of claim 1 wherein the physical conditioning of the greige includes the widthwise stretching of the greige prior to the application the polyurethane mixture.
 3. The method of manufacturing a laminated carpet product of claim 1 wherein the physical conditioning of the greige includes the heating of the greige prior to the application of the polyurethane mixture.
 4. The method of manufacturing a laminated carpet product of claim 1 wherein the physical conditioning of the greige includes the policing of the backstitch side of the greige to remove loose yarn segments prior to the application the polyurethane mixture.
 5. The method of manufacturing a laminated carpet product of claim 1 wherein the secondary backing receives an adhesion treatment prior to contacting the polyurethane mixture coated backstitch side of the greige.
 6. The method of manufacturing a laminated carpet product of claim 5 wherein the adhesion treatment is a plasma treatment.
 7. The method of manufacturing a laminated carpet product of claim 1 wherein steam is applied to the polyurethane coated backstitch side of the greige prior to contacting the secondary backing.
 8. A method for manufacturing a laminated carpet product using a polyurethane roller annealing system to join a greige having a face and an opposed backstitched side with a secondary backing comprising: (a) feeding a greige; (b) physically conditioning the greige by stretching the greige widthwise and policing the backstitch side of the greige to remove loose yarn pieces; (c) applying a polyurethane mixture with the roller annealing system as the greige is moved laterally with respect to the rollers to form a coating on the backstitch side of the greige; (d) contacting a secondary backing to the polyurethane mixture coated backstitch side of the greige to form a backed greige; and (e) feeding the secondary backing side of the backed greige substantially around the circumference of a heated drum.
 9. The method of manufacturing a laminated carpet product of claim 8 wherein a load cell reading loads as the greige is fed on to the heated drum, provides signals to keep the heated drum rotating at a speed sufficient to tension the backed greige to tend to hold the backing side against the surface of the heated drum.
 10. The method of manufacturing a laminated carpet product of claim 9 wherein the load cell signals require greater tension for relatively heavier greige and lesser tension for relatively lighter greige.
 11. The method of manufacturing a laminated carpet product of claim 8 wherein when the greige is passing over the lower side of the heated drum, a support is used to hold the greige against the drum.
 12. The method of manufacturing a laminated carpet product of claim 10 wherein the support is a press roller.
 13. The method of manufacturing a laminated carpet product of claim 8 wherein the secondary backing receives a plasma adhesion treatment prior to contacting the polyurethane mixture coated backstitch side of the greige.
 14. A method for manufacturing a laminated carpet product using a polyurethane roller annealing system to join a greige having a face and an opposed backstitched side with a secondary backing comprising: (a) feeding a greige; (b) physically conditioning the greige; (c) adhesively conditioning the secondary backing with a plasma treatment; (d) applying a polyurethane mixture with the roller annealing system as the greige is moved laterally with respect to the rollers to form a coating on the backstitch side of the greige; (e) contacting a secondary backing to the polyurethane mixture coated backstitch side of the greige to form a backed greige; (f) feeding the secondary backing side of the backed greige substantially around the circumference of a heated drum; and (g) supporting the greige on the lower side of the heated drum to hold the greige against the drum.
 15. The method of manufacturing a laminated carpet product of claim 14 including tensioning the backed greige to tend to hold the backing side against the surface of the heated drum.
 16. The method of manufacturing a laminated carpet product of claim 14 wherein steam is applied to the polyurethane coated backstitch side of the greige prior to contacting the secondary backing.
 17. The method of manufacturing a laminated carpet product of claim 14 wherein the physical conditioning of the greige includes the widthwise stretching of the greige and policing of the backstitch side of the greige to remove loose yarn segments prior to the application the polyurethane mixture.
 18. The method of manufacturing a laminated carpet product of claim 14 wherein steam is applied to the polyurethane coated backstitch side of the greige prior to contacting the secondary backing.
 19. The method of manufacturing a laminated carpet product of claim 14 wherein the physical conditioning of the greige includes the heating of the greige prior to the application of the polyurethane mixture.
 20. The method of manufacturing a laminated carpet product of claim 15 wherein tensioning is accomplished by load cell reading loads as the greige is fed on to the heated drum, and providing signals to keep the heated drum rotating at a speed sufficient to tension the backed greige to tend to hold the backing side against the surface of the heated drum. 